artículo de publicación periódica.page.titleprefix
Nanostructured rigid polyurethane foams with improved specific thermo-mechanical properties using bacterial nanocellulose as a hard Segment

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dc.contributor.authorChiacchiarelli, Leonel Matías
dc.contributor.authorBenavides, Sara
dc.contributor.authorArmanasco, Franco
dc.contributor.authorCerrutti, Patricia
dc.dateinfo:eu-repo/date/embargoEnd/2022-01-27
dc.date.accessioned2020-10-28T21:53:29Z
dc.date.available2020-10-28T21:53:29Z
dc.date.issued2021-01
dc.description.abstract"Bacterial nanocellulose (BNC) was used to synthesize rigid polyurethane foams (RPUFs) based on its reaction with the isocyanate precursor (ISO route) and also by using the conventional procedure (POL route). The results indicated that at only 0.1 wt. % of BNC, drastic improvements of specific elastic compressive modulus (+244.2 %) and strength (+77.5 %) were found. The reaction of BNC with the precursor was corroborated through the measurement of isocyanate number and the BNC caused a significant nucleation effect, decreasing the cell size up to 39.7%. DSC analysis revealed that the BNC had a strong effect on post-cure enthalpy, decreasing its value when the ISO route was implemented. DMA analysis revealed that the RPUFs developed using the ISO route proved to have an improved damping factor, regardless of BNC concentration. These results emphasize the importance of using the ISO route to achieve foamed nanocomposites with improved specific mechanical properties."en
dc.identifier.issn1097-4628
dc.identifier.urihttp://ri.itba.edu.ar/handle/123456789/3221
dc.language.isoenen
dc.relationinfo:eu-repo/semantics/altIdentifier/doi/10.1002/app.50520
dc.rightsinfo:eu-repo/semantics/embargoedAccess
dc.subjectCELULOSA BACTERIANAes
dc.subjectBIOPOLIMEROSes
dc.subjectESPUMASes
dc.titleNanostructured rigid polyurethane foams with improved specific thermo-mechanical properties using bacterial nanocellulose as a hard Segmenten
dc.typeArtículos de Publicaciones Periódicases
dc.typeinfo:eu-repo/semantics/acceptedVersion
dspace.entity.typeArtículo de Publicación Periódica
itba.description.filiationFil: Chiacchiarelli, Leonel Matías. Instituto Tecnológico de Buenos Aires; Argentina.
itba.description.filiationFil: Benavides, Sara. Universidad de Buenos Aires. Facultad de Ingeniería; Argentina.
itba.description.filiationFil: Benavides, Sara. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina.
itba.description.filiationFil: Armanasco, Franco. Universidad de Buenos Aires. Facultad de Ingeniería; Argentina.
itba.description.filiationFil: Armanasco, Franco. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina.
itba.description.filiationFil: Cerrutti, Patricia. Universidad de Buenos Aires. Facultad de Ingeniería; Argentina.
itba.description.filiationFil: Cerrutti, Patricia. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina.

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