Detection of chlorantraniliprole residues in tomato using field-deployable MIP photonic sensors

Rossi, Ezequiel; Salahshoor, Zahra; Ho, Khanh-Van; Lin, Chung-Ho; Errea, María Inés; Fidalgo de Cortalezzi, María Marta

Artículo de Publicación Periódica:
Detection of chlorantraniliprole residues in tomato using field-deployable MIP photonic sensors

dc.contributor.author	Rossi, Ezequiel
dc.contributor.author	Salahshoor, Zahra
dc.contributor.author	Ho, Khanh-Van
dc.contributor.author	Lin, Chung-Ho
dc.contributor.author	Errea, María Inés
dc.contributor.author	Fidalgo de Cortalezzi, María Marta
dc.date	info:eu-repo/date/embargoEnd/2022-02-05
dc.date.accessioned	2021-03-16T21:22:54Z
dc.date.available	2021-03-16T21:22:54Z
dc.date.issued	2021-02
dc.description.abstract	"A photonic sensor based on inversed opal molecular imprinted polymer (MIP) film to detect the presence of chlorantraniliprole (CHL) residue in tomatoes was developed. Acrylic acid was polymerized in the presence of CHL inside the structure of a colloidal crystal, followed by etching of the colloids and CHL elution. Colloidal crystals and MIP films were characterized by scanning electron microscopy and FT-IR, confirming the inner structure and chemical structure of the material. MIP films supported on polymethylmethacrylate (PMMA) slides were incubated in aqueous solutions of the pesticide and in blended tomato samples. The MIP sensor displayed shifts of the peak wavelength of the reflection spectra in the visible range when incubated in CHL concentrations between 0.5 and 10 μg L−1, while almost no peak displacement was observed for non-imprinted (NIP) films. Whole tomatoes were blended into a liquid and spiked with CHL; the sensor was able to detect CHL residues down to 0.5 μg kg−1, significantly below the tolerance level established by the US Environmental Protection Agency of 1.4 mg kg−1. Stable values were reached after about 30-min incubation in test samples. Control samples (unspiked processed tomatoes) produced peak shifts both in MIP and NIP films; however, this matrix effect did not affect the detection of CHL in the spiked samples. These promising results support the application of photonic MIP sensors as an economical and field-deployable screening tool for the detection of CHL in crops."	en
dc.identifier.issn	1436-5073
dc.identifier.uri	http://ri.itba.edu.ar/handle/123456789/3414
dc.language.iso	en	en
dc.relation	info:eu-repo/semantics/altIdentifier/doi/10.1007/s00604-021-04731-2
dc.rights	info:eu-repo/semantics/embargoedAccess
dc.subject	POLIMEROS	es
dc.subject	PLAGUICIDAS	es
dc.subject	TOMATE	es
dc.title	Detection of chlorantraniliprole residues in tomato using field-deployable MIP photonic sensors	en
dc.type	Artículos de Publicaciones Periódicas	es
dc.type	info:eu-repo/semantics/acceptedVersion
dspace.entity.type	Artículo de Publicación Periódica
itba.description.filiation	Fil: Rossi, Ezequiel. Instituto Tecnológico de Buenos Aires; Argentina.
itba.description.filiation	Fil: Rossi, Ezequiel. University of Missouri--Columbia; Estados Unidos.
itba.description.filiation	Fil: Salahshoor, Zahra. University of Missouri--Columbia; Estados Unidos.
itba.description.filiation	Fil: Ho, Khanh-Van. University of Missouri--Columbia; Estados Unidos.
itba.description.filiation	Fil: Ho, Khanh-Van. Đại học Cần Thơ; Vietman.
itba.description.filiation	Fil: Lin, Chung-Ho. University of Missouri--Columbia; Estados Unidos.
itba.description.filiation	Fil: Errea, María Inés. Instituto Tecnológico de Buenos Aires; Argentina.
itba.description.filiation	Fil: Fidalgo de Cortalezzi, María Marta. University of Missouri--Columbia; Estados Unidos.